USGS-NWQL: I-1586:  pH in Water by Electrometry Using a Glass-Electrode

  • Summary
  • Analytes
  • Revision
  • Data and Sites
Official Method Name
pH in Water by Electrometry Using a Glass-Electrode
Current Revision
1985
Media
WATER
Instrumentation
pH Meter
Method Subcategory
Inorganic
Method Source
  USGS-NWQL
Citation
Methods for the Determination of Inorganic Substances in Water and Fluvial Sediments, Techniques of Water-Resources Investigations of the United States Geological Survey, Book 5, Chapter A1 Edited by Marvin J. Fishman and Linda C. Friedman
Brief Method Summary
This method involves pH-meter operation and may be automated with commercially available instrumentation.
Scope and Application
This method may be used to determine the pH of any natural or treated water and any industrial or other wastewater.
Applicable Concentration Range
None given.
Interferences
(1) Sodium error may bias results at pH > 10 unless a "low sodium error" electrode is used. (2) Coatings of oily material can impair electrode. (3) Temperature effects.
Quality Control Requirements
Calibrate instrument using calibration standards (CAL); quality control samples (QCS); and laboratory blanks (LB) analyzed at a minimum of 1 for every 10 samples.
Sample Handling
Container Description: 125 mL polyethylene bottle.
Treatment and Handling: Use unfiltered sample to rinse bottle. Max holding time: 180 days.
Maximum Holding Time
180 days
Relative Cost
Less than $50
Sample Preparation Methods