EPA-NERL: 212.3:  Boron by Colorimetry

  • Summary
  • Analytes
  • Revision
  • Data and Sites
Official Method Name
Boron (Colorimetric, Curcumin)
Current Revision
Issued 1974
Media
WATER
Instrumentation
Spectroscopy (Colorimetry; Photometry)
Method Subcategory
Inorganic
Method Source
  EPA-NERL
Citation
  Methods for the Chemical Analysis of Water and Wastes (MCAWW) (EPA/600/4-79/020)
Brief Method Summary
When a sample of water containing boron is acidified and evaporated in the presence of curcumin, a red-colored product called rosocyanine is formed. The rosocyanine is taken up in a suitable solvent, and the red color (which is proportional to colorimetry) is compared with standards photometrically.
Scope and Application
This method determines boron in drinking waters, surface waters, domestic and industrial wastes.
Applicable Concentration Range
0.1-1.0 mg/L (optimal range).
Interferences
(A) Nitrate: Nitrate above 20 mg/L can interfere.
(B) Hardness: Hardness above 100 mg/L can interfere. Passing the sample through a cation exchange resin eliminates this problem.
Quality Control Requirements
None.
Sample Handling
Maximum Holding Time
6 months (MCAWW, Table 1).
Relative Cost
Less than $50
Sample Preparation Methods
None.