EPA-NERL: 212.3: Boron by Colorimetry
Official Method Name
|
Boron (Colorimetric, Curcumin) |
---|---|
Current Revision
| Issued 1974 |
Media
|
WATER |
Instrumentation
|
Spectroscopy (Colorimetry; Photometry) |
Method Subcategory
|
Inorganic |
Method Source
|
|
Citation
|
|
Brief Method Summary
|
When a sample of water containing boron is acidified and evaporated in the presence of curcumin, a red-colored product called rosocyanine is formed. The rosocyanine is taken up in a suitable solvent, and the red color (which is proportional to colorimetry) is compared with standards photometrically. |
Scope and Application
|
This method determines boron in drinking waters, surface waters, domestic and industrial wastes. |
Applicable Concentration Range
|
0.1-1.0 mg/L (optimal range). |
Interferences
|
(A) Nitrate: Nitrate above 20 mg/L can interfere. (B) Hardness: Hardness above 100 mg/L can interfere. Passing the sample through a cation exchange resin eliminates this problem. |
Quality Control Requirements
|
None. |
Sample Handling
|
|
Maximum Holding Time
|
6 months (MCAWW, Table 1). |
Relative Cost
|
Less than $50 |
Sample Preparation Methods
|
None. |