EPA-NERL: 375.4:  Sulfate by Turbidity

  • Summary
  • Analytes
  • Revision
  • Data and Sites
Official Method Name
Sulfate (Turbidimetric)
Current Revision
Issued 1971; Editorial Revision 1978
Media
WATER
Instrumentation
Turbidity
Method Subcategory
Inorganic
Method Source
  EPA-NERL
Citation
  Methods for the Chemical Analysis of Water and Wastes (MCAWW) (EPA/600/4-79/020)
Brief Method Summary
A sample is treated with barium chloride to form a barium sulfate suspension under controlled conditions. The resulting turbidity from the suspension is measured with a nephelometer, and the response is compared to a sulfate standard curve.
Scope and Application
This method determines sulfate in drinking and surface waters; domestic and industrial wastes.
Applicable Concentration Range
1 to 40 mg sulfate/L
Interferences
(A) Turbidity and Color: Turbidity and color natural to the sample can interfere. Interferences can be mitigated by running sample blanks from which barium chloride has been omitted.
(B)Silica: Silica at concentrations greater than 500 mg/L will interfere.
Quality Control Requirements
None.
Sample Handling
Refrigerate samples at 4oC.
Maximum Holding Time
28 Days (MCAWW, Table 1).
Relative Cost
Less than $50
Sample Preparation Methods