EPA-NERL: 150.2:  pH in Water

  • Summary
  • Analytes
  • Revision
  • Data and Sites
Official Method Name
pH, Continuous Monitoring (Electrometric)
Current Revision
December 1982
Media
WATER
Instrumentation
pH Meter
Method Subcategory
Inorganic
Method Source
  EPA-NERL
Citation
  Methods for the Chemical Analysis of Water and Wastes (MCAWW) (EPA/600/4-79/020)
Brief Method Summary
The pH of a sample is determined electrometrically using a glass electrode with a reference electrode or a single combination electrode.
Scope and Application
This method continuously determines pH in drinking, surface, and saline waters; domestic and industrial waste waters.
Applicable Concentration Range
None Provided
Interferences
(A) Coating: Inspect electrodes every 30 days to ensure there is not a build-up of oily material or lime on the electrode. Clean electrodes with dilute HCl as required.
(B) Temperature: Temperature effects must be compensated for.
(C) Sodium: error at pH levels greater than 10 can be reduced or eliminated by using a "low sodium error" electrode.
Quality Control Requirements
None.
Sample Handling
The composition of the water or waste contacting the measuring electrode system must be representative of the total flow from the water body.
Maximum Holding Time
Not Applicable.
Relative Cost
Less than $50
Sample Preparation Methods